Steel Protection
By Hot Dip Galvanizing & Duplex Systems

Information courtesy of: HOT DIP GALVANIZERS ASSOCIATION SOUTHERN AFRICA

Choice of Rust Prevention Method

When choosing a rust prevention method for a steel component or structure, there are many technical issues to be addressed. The environment in which the steel component or structure is to work must be analysed carefully. The need for handling, transport, fabrication and final erection require careful consideration.

The reliability factor of a coating may be defined as the extent to which its physical, chemical and mechanical characteristics can be consistently realised during and after application.

The reliability factor determines the overall cost-effectiveness of a coating in an environment.

There are numerous paint systems for steel and a wide range of possible specification and application variables. These variables can substantially reduce the performance of a given system and therefore its economics. By contrast, the hot dip galvanizing process is simple, standardised and virtually self-controlling, governed mainly by the laws of metallurgy. As a result it is inherently reliable and predictable.

Table 1 summarises factors determining the reliability of typical paint systems for steel, and for hot dip galvanizing. The reliability factor for hot dip galvanizing is shown to be superior, mainly because it is not influenced by most of the variables which can reduce the ultimate performance of typical paint systems.

Figure 5. Hot dip galvanized handrail and vastrap stairs.

Since paints are available in countless variations, with different properties, conditions and demands being variable in practice, a comparison with actual parameters is often advisable.

Further, an economic study of different prevention methods should be undertaken. It is important that the choice of method be based not only on initial costs but also on packing costs for transportation, touch-up painting after erection and future maintenance costs.

A good guide to the selection of corrosion prevention methods in different environments can be found in SABS ISO 14713 - Protection Against Corrosion of Iron and Steel Structures -Zinc and Aluminium Coatings - Guidelines and in SABS ISO 12944 Parts 1 - 8 - Corrosion Protection of Steel Structures by Protective Paint Systems.

The environmental classifications defined in these standards concern only the environment in which the structure will function. However, transportation, storage and erection environments can change the environmental classification, and therefore the choice of rust prevention method.

Figure 6 serves as a guide for comparing the technical characteristics of different types of coating.

It should be noted that, even if zinc and paint are applied with the same objective - to prevent corrosion - they act in completely different ways. The zinc coating corrodes from the surface in towards the steel, and gives cathodic protection in the event of damage to the coating. Corrosion does not occur between the zinc coating and the steel.

Conversely, paint coatings are often destroyed through the development of a layer of rust between the paint and the steel. Since the paint coating gives no cathodic protection, rust is able to penetrate further beneath the paint coating once the coating has been damaged.

Figure 6. Comparison between the properties of different surface coatings.

Factor Point System Hot Dip Galvanizing
Preparation ISO 8501-1:1988 prescribes abrasive blasting to So 2 . Unsatisfactory cleaning can reduce the service life of the point system by 60-80%. Preparation control is of decisive significance. Pickling in acid is an essential port of the process. If the surface is not clean, no coating will be formed. Preparation control is not essential.
Process Careful formulation, mixing, agitation and correct thinning are factors of great significance. The small variations that are possible have little or no influence on the quality of the zinc coaling.
Application The composition and uniformity of the coating varies with the method of application. Inspection of each stage of application is important. Abrasively-Hasted surfaces are reactive and must be painted very soon after blasting. The zinc coating is formed through a reaction between iron and zinc. The reaction is controlled by physical and chemical laws.
Application Conditions
1. Temperature Good results are difficult to obtain if the air temperature is below 4-10C. Surfaces exposed to direct sunlight can easily become too hot. Not affected by the air temperature or normal variations in the process temperature.
2. Humidity Dew and surface condensation delay pointing, which should not be carried out if relative humidity exceeds 80%. Not affected.
3. Air pollution Steam, fumes, gases, dust and other pollutants have an adverse effect on the quality of the paint coating. Not affected.
Type of steel No influence. The content of, primarily, silicon and phosphorous in the steel affects the thickness and appearance of the coating.
Properties of the Coating
1. Thickness Of great significance to service life. Varies with the number of layers and method of application. Inspection of thickness important for each layer. The reaction between molten zinc and iron gives a certain standard minimum thickness. Silicon and phospheraus content at certain levels in steel, increased mass, material thickness and surface roughness give increased coating thickness.
2. Adhesion Depends on preparation, type of paint system, interval between preparation and priming and hardening interval between layers. The zinc coating is bound to the steel metallurgically.
3. Uniformity The point coating is thinner over corners and sharp edges. Holes and narrow crevices normally remain uncoated. "Shaded' sections can be subject to thinner layers. Total uniform coverage through dipping in molten zinc. Coating generally 50% thicker over sharp edges.
Hardening time Can vary, depending on type of paint and application conditions, from a few hours to several days for good handling characteristics, and up to several weeks for ultimate hardness. The coating hardens completely within a few seconds of withdrawal from the zinc bath.
Dimensional Stability None. Built-in stresses caused by cold-working or welding can, in certain cases, be released so that some deformation occurs.
Inspection Must be carried out after preparation and after each stage in the treatment to ensure good quality. Inspection of layer thickness upon application and on finished goods. Visual control and measuring of layer thickness after treatment.
Risk of damage during transportation and handling Great. Can necessitate repair to primer coating and complete overcoating. Small. Coating withstands high mechanical stress. Minor damage does not need to be repaired. More serious damage must be repaired by means of zinc metal spraying or coating with zinc-rich paint or epoxy.

Table 1 - Comparison of the properties between a paint system and hot dip galvanizing.

Table 2. Zinc coatings compared in tennis of coaling thickness and relative life expectancy

COMPATIBILITY OF GALVANIZED COATINGS WITH VARIOUS MEDIA

Compatibility of lion dip galvanized coatings with various media is summarised in the table below. Further specific information is available front Hot Dip Galvanizers Association Southern Africa.

Aerosol propellants   excellent
Acid solutions down to pH 6.0
strong
fair
not recommended
Alcohols anhydrous
water mixtures
beverages
good
not recommended
not recommended
Alkaline solutions up to pH 12.6
strong
fair
not recommended
Detergents inhibited good
Diesel oil sulphur free excellent
Fuel oil sulphur free excellent
Gas towns, natural, propane, butane excellent
Glycerine   excellent
Inks printing
aqueous writing
excellent
not recommended
Insecticides dry
in solution
excellent
not recommended
Lubricants mineral, acid free
organic
excellent
not recommended
Paraffin   excellent
Refrigerants   excellent
Sewage   excellent*
Fertilizers dry
aqueous
good
use with care
Timber preservatives Copper-chromium-arsenic, freshly treated
After drying is completed
Boron
poor
excellent
excellent
Trichlorethylene   excellent

*Anaerobic conditions to be as-aided.

Sewage Treatment

Hot dip galvanized coatings perform extremely welt by comparison with other protective
coatings far steel in the severely corrosive conditions prevailing in most sewage treatment
operations. As a result hot dip galvanized steel is used extensively in sewage treatment
plants throughout the world.

Table 3. Compatibility of hot dip galvanized coatings with various media.

General Information About Zinc
Atomic Weight 65.37
Density  
 - rolled - 25C 7192 kg/m3
 - cast - 25C 6804 kg/m3
 - liquid 6620 kg/m3
Melting Point 419.5C
Boiling Point 907C
Appearance bluish-white metal
Atomic Number 30
Modulus of elasticity 7 x 104 MN/m2
Specific Heat 0.382 kJ/kg.K
Latent heat of fusion (419.5C) 100.9 kJ/kg
Latent heat of vapourisation (906C) 1.782 MJ/kg
Heat capacity  
 - Solid 22.40 + 10.5 x 10-3 TJ/mol
 - Liquid 31.40 J/mol
 - Gas 20.80 J/mol
Linear coefficient of thermal expansion (20-400C) 39.7 m/m.K
Volume coefficient of thermal expansion (20-400C) 0.89 x 106/K
Thermal conductivity: solid (18C) 113 W/m.K
Electrical resistivity (20C) 5.9 uΩm
Standard electrode potential (H2 electrode) -0.762 V
Enthalpy of Vapourisation 114.2 kJ/mol

Table 4. Properties of zinc.